Using deuteriated substrate and reagent, it was shown that the backbone rearrangement of des-A-steroidal hydroxy-olefins does not proceed through protonation–deprotonation of intermediate olefins or cyclopropanes.
J. P. Berthelot and J. Levisalles, J. Chem. Soc. D, 1970, 1162 DOI: 10.1039/C29700001162
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