Issue 18, 1970

Pummerer rearrangement of 1,3-oxathiolan-5-one S-oxides

Abstract

In their reaction with acetic anhydride, 2,2-dialkyl-1,3-oxathiolan-5-one S-oxides give by a highly stereoselective process the corresponding 4-acetoxy-2,2-dialkyl-1,3-oxathiolan-5-ones, in which the acetoxy-group is introduced on the side of the ring formerly occupied by the S-oxide bond.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1158-1158

Pummerer rearrangement of 1,3-oxathiolan-5-one S-oxides

S. Glue, I. T. Kay and M. R. Kipps, J. Chem. Soc. D, 1970, 1158 DOI: 10.1039/C29700001158

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