Issue 18, 1970

Stereospecific radical–radical-anion combination in the reductive aminoalkylation of anthracene

Abstract

The aminoalkylation of lithium dihydroanthracenylide occurs with complete retention of the configuration and the CαCN bond-breaking involves sp3sp2 hybridisation change; the most consistent explanation of these results is the directing effect of LiCN on the radical–radical-anion combination.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1149-1150

Stereospecific radical–radical-anion combination in the reductive aminoalkylation of anthracene

C. Fabre, H. Ali and Z. Welvart, J. Chem. Soc. D, 1970, 1149 DOI: 10.1039/C29700001149

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