The thermal catalytic decomposition of N2O on ZnO in the range 370–430° is first order in N2O pressure and independent of O2 pressure while the photocatalytic reaction at the same temperatures obeys an expression of the type rate =kP(N2O)/k′+k″P(N2O)+k‴[P(O)2)]1/2.
K. Tanaka and G. Blyholder, J. Chem. Soc. D, 1970, 1130 DOI: 10.1039/C29700001130
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