Several new organorhodium compounds derived from the reaction of quadricyclene with di-µ-chlorotetracarbonyldirhodium(I) are described; it is concluded that the rhodium(I)-catalysed valence isomerization of quadricyclene to norbornadiene proceeds through a non-concerted mechanism involving an oxidative addition step.
L. Cassar and J. Halpern, J. Chem. Soc. D, 1970, 1082 DOI: 10.1039/C29700001082
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