A single-crystal X-ray diffraction study of [(π-C5H5)Fe(CO)2(C8H8)+][SbF6–] shows the heptafulvene moiety to be bonded to the iron atom via an iron–carbon σ-bond, the cationic charge thus residing within the conjugated seven-membered ring of the heptafulvene system.
M. R. Churchill and J. P. Fennessey, J. Chem. Soc. D, 1970, 1056 DOI: 10.1039/C29700001056
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