The predominant mechanism of decomposition of monoalkylthallium(III) halides in pyridine solution involves bimolecular displacement of thallium(I) by attack of halide ion or pyridine on the alkyl group; hence, mono-neopentylthallium(III) halides are relatively stable.
M. D. Johnson, J. Chem. Soc. D, 1970, 1037 DOI: 10.1039/C29700001037
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