Issue 16, 1970

A new type of intramolecular group-transfer in steroid photochemistry. A contribution to the mechanism of the oxidative cyanohydrin–cyano-ketone rearrangement

Abstract

A radical-induced intramolecular transfer of a cyano-group is initiated by photolysis of a nitrite function situated in the ε-position with respect to the migrating group.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1002-1003

A new type of intramolecular group-transfer in steroid photochemistry. A contribution to the mechanism of the oxidative cyanohydrin–cyano-ketone rearrangement

J. Kalvoda, J. Chem. Soc. D, 1970, 1002 DOI: 10.1039/C29700001002

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