Formation of alkyl–metal compounds by displacement of halide ion from alkyl halides by transition-metal nucleophiles occurs with inversion of configuration; cleavage of the carbon–metal bond with bromine occurs with retention of configuration.
R. W. Johnson and R. G. Pearson, J. Chem. Soc. D, 1970, 986 DOI: 10.1039/C29700000986
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