Issue 16, 1970

Hindered rotation about C–N bonds: equilibration of diastereomeric rotational isomers

Abstract

The equilibration of diastereomeric rotational isomers of 4,6-diamino-1,2-dihydro-2-methyl-1-(o-tolyl)-s-triazine hydrochloride (I), and 5-methyl-3-α-naphthyl-2-thiohydantoin (II) has been followed by integration of their n.m.r. spectra, and the activation parameters for hindered rotation about C–N bonds have been calculated.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 974-974

Hindered rotation about C–N bonds: equilibration of diastereomeric rotational isomers

W. E. Bentz, L. D. Colebrook, J. R. Fehlner and A. Rosowsky, J. Chem. Soc. D, 1970, 974 DOI: 10.1039/C29700000974

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