Deuterium-labelling experiments demonstrate that the additions of benzyne to cyclopentadienyl- and to indenyl-magnesium bromide are the first well-established examples of intermolecular [π4s+π2s] cycloadditions of allyl anions to alkenes.
W. T. Ford, R. Radue and J. A. Walker, J. Chem. Soc. D, 1970, 966 DOI: 10.1039/C29700000966
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