Enhanced reactivity of nucleophiles: orbital symmetry and the so-called “α-effect”
Abstract
Two explanations of the “α-effect” are advanced: (a) electron repulsion due to pπ–pπ overlap and (b) intramolecular catalysis when (a) cannot operate.
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Article information
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- Paper
J. Chem. Soc. D, 1970, 937-938
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Enhanced reactivity of nucleophiles: orbital symmetry and the so-called “α-effect”
J. D. Aubort and R. F. Hudson, J. Chem. Soc. D, 1970, 937 DOI: 10.1039/C29700000937
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