Issue 15, 1970

A possible azirine intermediate in the reaction of bromonitroalkenes with triphenylphosphine

Abstract

Bromonitroalkenes react with triphenylphosphine in benzene to give α-cyanoalkyltriphenylphosphonium bromides: the same reaction in methanol gives a rearranged product (IV), the formation of which is most easily rationalised via an azirine intermediate.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 917-918

A possible azirine intermediate in the reaction of bromonitroalkenes with triphenylphosphine

C. J. Devlin and B. J. Walker, J. Chem. Soc. D, 1970, 917 DOI: 10.1039/C29700000917

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