Issue 15, 1970

An ambident carbanion stabilized by bivalent sulphur

Abstract

2-α-Styryl-1,3-dithian reacts with strong bases to yield an ambident carbanion: the importance of sulphur 3d-orbital conjugation in the stabilization of such ambident carbanions is assessed with CNDO calculations.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 913-914

An ambident carbanion stabilized by bivalent sulphur

D. L. Coffen, T. E. McEntee and D. R. Williams, J. Chem. Soc. D, 1970, 913 DOI: 10.1039/C29700000913

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements