The circular dichroism and the chirality of the unsymmetric-cis- and the trans-(+)D-bis(diethylenetriamine)cobalt(III) ion
Abstract
The circular dichroism of the systems u-cis-(+)D-[Co(dien)2]3+ and trans-(+)D-[Co(dien)2]3+ indicates the stereochemical configuration of the former, and indicates in the latter a new type of chirality which has hitherto not been realized, but which will be present in metal–polyamine complexes.
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