An attempted carbene insertion reaction within a tricarbonyl iron π-complex gave an unexpected rearrangement product: X-ray structure analysis showed it to be an intramolecular “head-to-tail” bonded iron σ,π-complex exhibiting interesting bonding geometry.
P. Janse-van Vuuren, R. J. Fletterick, J. Meinwald and R. E. Hughes, J. Chem. Soc. D, 1970, 883 DOI: 10.1039/C29700000883
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