A new route to the palladium hydride complexes, trans-(R13P)22PdHCl, R1= cyclohexyl or isopropyl, is described involving use1 of a hydridoborohydride complex, trans-(R13P)2MH(BH4), M = Ni or Pd, as a reducing agent and a tertiary phosphine ligands exchange reaction.
H. Munakata and M. L. H. Green, J. Chem. Soc. D, 1970, 881 DOI: 10.1039/C29700000881
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