Electrochemical oxidation of known dinitrogen complexes in aqueous solution has been shown to produce transient [Os(NH3)5N2]3+ and [(NH3)5RuN2Ru(NH3)5]5+ species with decomposition rate constants of 0·02 sec–1 and 0·10 sec–1, respectively; no [Ru(NH3)5N2]3+ was detected.
C. M. Elson, J. Gulens, I. J. Itzkovitch and J. A. Page, J. Chem. Soc. D, 1970, 875 DOI: 10.1039/C29700000875
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