Loganin and indole alkaloids are efficiently biosynthesised in Vinca rosea from 10-hydroxygeraniol (16) and 10-hydroxynerol (18) with considerable randomisation of C-9 and C-10.
S. Escher, P. Loew and D. Arigoni, J. Chem. Soc. D, 1970, 823 DOI: 10.1039/C29700000823
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