A binuclear dihydride of iron, H2Fe2(CO)6[P(CF3)2]2
Abstract
The reaction of Fe(CO)5 or Fe3(CO)12 with (CF3)2PH gives H2Fe2(CO)6[P(CF3)2]2, which exists as a mixture of cis- and trans-isomers in solution.
The reaction of Fe(CO)5 or Fe3(CO)12 with (CF3)2PH gives H2Fe2(CO)6[P(CF3)2]2, which exists as a mixture of cis- and trans-isomers in solution.
R. C. Dobbie and D. Whittaker, J. Chem. Soc. D, 1970, 796 DOI: 10.1039/C29700000796
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