Allyltrimethylsilane was thermolysed to vinyltrimethylsilane at 500° with loss of the methylene group, the latter being inserted into an Si–H bond of RMe2Si–H by forming RMe2Si–Me.
H. Sakurai, A. Hosomi and M. Kumada, J. Chem. Soc. D, 1970, 767 DOI: 10.1039/C29700000767
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