The stereochemical direction of nucleophilic displacements at phosphorus in phospholanium ions is shown to depend on the nature of the entering and leaving groups, as well as on constraints imposed by the ring.
W. Egan, G. Chauvière, K. Mislow, R. T. Clark and K. L. Marsi, J. Chem. Soc. D, 1970, 733 DOI: 10.1039/C29700000733
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