Dicobalt octacarbonyl reacts with triethynylarsine to produce a crystalline, air-stable complex, shown by single-crystal X-ray analysis to have three hexacarbonyldicobalt fragments π-bonded to the ethynyl groups.
P. H. Bird and A. R. Fraser, J. Chem. Soc. D, 1970, 681 DOI: 10.1039/C29700000681
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