Issue 10, 1970
From the journal:

Journal of the Chemical Society D: Chemical Communications

The redox nature of the reaction of β-rhenium(IV) chloride with triphenylphosphine in acetonitrile, and the crystal structure of the reduction product trichloro(acetonitrile)bis(triphenylphosphine)rhenium(III)

M. G. B. Drew,   D. G. Tisley  and  R. A. Walton  

Abstract

An unusual redox reaction of β-rhenium(IV) chloride with triphenylphosphine in acetonitrile is described, and the crystal structure of one of the reduction products, ReCl3,2PPh3,MeCN shows that this molecule contains σ-bonded acetonitrile.

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Article information

DOI
https://doi.org/10.1039/C29700000600
Article type
Paper

J. Chem. Soc. D, 1970, 600-601

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The redox nature of the reaction of β-rhenium(IV) chloride with triphenylphosphine in acetonitrile, and the crystal structure of the reduction product trichloro(acetonitrile)bis(triphenylphosphine)rhenium(III)

M. G. B. Drew, D. G. Tisley and R. A. Walton, J. Chem. Soc. D, 1970, 600 DOI: 10.1039/C29700000600

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