The signs of the Cotton Effects associated with each of the mono-olefinic centres in taxane derivatives can be used to assign the absolute configuration of the molecule.
D. P. D. C. de Marcano, T. G. Halsall, A. I. Scott and A. D. Wrixon, J. Chem. Soc. D, 1970, 582 DOI: 10.1039/C29700000582
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