One-to-one complexes of the ligands (o-styryl)3P and (o-styryl)3As with RhX (X = Cl, Br, I) have been prepared: their properties indicate a pentaco-ordinate trigonal bipyramidal structure with the three olefin groups occupying the three trigonal (C3), and the halogen and phosphorus (or arsenic) atoms the apical, positions.
D. I. Hall and R. S. Nyholm, J. Chem. Soc. D, 1970, 488 DOI: 10.1039/C29700000488
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