In the crystal form of tetrakiscyclopentadienylzirconium, three cyclopentadienyl rings are π-bonded at a mean Zr–C distance of 2·64 Å, the fourth ring being σ-bonded with a Zr–C distance of 2·47 Å.
V. I. Kulishov, E. M. Brainina, N. G. Bokiy and Yu. T. Struchkov, J. Chem. Soc. D, 1970, 475 DOI: 10.1039/C29700000475
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