The yield of addition of a Grignard reagent to a hindered ketone has been enhanced at the expense of reduction by complexing the Grignard reagent with lithium perchlorate or tetrabutylammonium bromide.
M. Chastrette and R. Amouroux, J. Chem. Soc. D, 1970, 470 DOI: 10.1039/C29700000470
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