Nitrogen inversion barriers and structural effects on the barriers have been studied by variable temperature n.m.r. spectroscopy in monocyclic (six- and seven-membered ring) and bicyclic (bicyclo[2,2,2]octane and bicyclo[3,2,2]nonane) amines.
J. M. Lehn and J. Wagner, J. Chem. Soc. D, 1970, 414 DOI: 10.1039/C29700000414
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