A variable temperature nuclear magnetic resonance spectroscopy study of nitrogen inversion in medium-ring monocyclic and bicyclic systems
Abstract
Nitrogen inversion barriers and structural effects on the barriers have been studied by variable temperature n.m.r. spectroscopy in monocyclic (six- and seven-membered ring) and bicyclic (bicyclo[2,2,2]octane and bicyclo[3,2,2]nonane) amines.