The anionic pentasulphide chain S52– acts as a bidentate ligand to form the “hetero-cyclohexahalcogen”(C5H5)2TiS5: the TiS5 ring fragment has the chair conformation with Ti–S bond lengths of 2·420 and 2·446 Å and S–S bond lengths which range from 2·051–2·059 Å.
E. F. Epstein and I. Bernal, J. Chem. Soc. D, 1970, 410 DOI: 10.1039/C29700000410
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