At very low interfacial velocities, the free energy per unit area of the P.T.F.E.–water interface includes both dispersive and polar components, while at higher velocities only the dispersive forces need be considered.
A. C. Lowe and A. C. Riddiford, J. Chem. Soc. D, 1970, 387 DOI: 10.1039/C29700000387
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