The unsym-trialkylboranes derived from alk-1-enes and dicyclohexyl- or bis-(1,2-dimethylpropyl)-borane can be treated with aqueous alkaline mercuric oxide followed by in situ bromination to afford good yields of primary alkyl halides.
J. J. Tufariello and M. M. Hovey, J. Chem. Soc. D, 1970, 372 DOI: 10.1039/C29700000372
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