Infrared evidence suggests that photolysis of Mn(CO)4NO in an argon matrix at 15°K produces CO and metal nitrosyl species which recombine with CO when the temperature is raised from 15°K to 30°K.
A. J. Rest, J. Chem. Soc. D, 1970, 345 DOI: 10.1039/C29700000345
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