The reactions of Fe3(CO)12 with the secondary and tertiary alkyl thiols RSH (R = Pri, Bus, and But) in refluxing benzene afford the novel bridged sulphido-derivatives Fe3(CO)9(H)(SR), Fe3(CO)9(SBut)2, and Fe4(CO)12(SBut)2(S).
J. A. de Beer and R. J. Haines, J. Chem. Soc. D, 1970, 288 DOI: 10.1039/C29700000288
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