cis- and trans-9,10-Dimethyl-9,10-disiladecalin. Synthesis and oxidation with peroxides
Abstract
The title compounds, prepared from cis- and trans-1,2-difluoro-1,2-dimethyl-1,2-disilacyclohexane with BrMg[CH2]4MgBr, undergo oxidation with perbenzoic acid or bis(trimethylsilyl) peroxide to give cis-1,6-dimethyl-11-oxa-1,6-disilabicyclo[4,4,1]undecane.