An apparently general, hitherto unobserved reaction pathway for α-oximino-ketones, mechanistically related to the Semmler–Wolff aromatization, is described and put in the framework of “non-Beckmannian reactions”; a novel explanation is suggested for the formation, in Ac2O–AcOH–HCl, of anomalous Beckmann rearrangement products.
E. Galantay, C. Hoffman and N. Paolella, J. Chem. Soc. D, 1970, 274 DOI: 10.1039/C29700000274
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