The trans-isomers of dihalogenobis(triphenylphosphine)platinum(II) complexes, difficult to obtain by other methods, are readily synthesized by photochemical isomerization of the cis-complexes: this method can also be applied to other platinum(II) complexes.
S. H. Mastin and P. Haake, J. Chem. Soc. D, 1970, 202 DOI: 10.1039/C29700000202
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