SCHEDULED MAINTENANCE
Magnetic resonance of protons in methionine and water bound to copper(II) has shown that, in solution, as in the solid, the methionine is co-ordinated via N and O and not via S; the complexes are CuA(H2O)4+ and CuA2(H2O)2: however, CuII is bound by S in many other potentially bidentate and tridentate thiocarboxylates.
M. R. Harrison and F. J. C. Rossotti, J. Chem. Soc. D, 1970, 175 DOI: 10.1039/C29700000175
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