The values of the reduction potentials of a series of nickel diketone bisthiosemicarbazones are shown to depend on the ligand substituents and on the extent of conjugation within the ligand framework: the structures of two complexes containing a seven-membered chelate ring have been determined by X-ray techniques.
N. A. Bailey, S. E. Hull, C. J. Jones and J. A. McCleverty, J. Chem. Soc. D, 1970, 124 DOI: 10.1039/C29700000124
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