The stable radical anions (I·–) absorb oxygen to form a diamagnetic peroxide –I·O·O·I–, whose photolysis (500–700 nm) leads to the rupture of a C–O bond and reformation of 1/2 of the original radical-ions without evolution of oxygen.
W. Bracke, J. Chaudhuri, J. Jagur-Grodzinski and M. Szwarc, J. Chem. Soc. D, 1970, 77 DOI: 10.1039/C29700000077
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