A tetrahydropyran-2-yloxy-group activates a double bond in a cyclohexene or cyclohexadiene system in a similar way to an amino-group, and thermal reactions with αβ-unsaturated carbonyl derivatives result in good yields of 2-substituted cyclohexanones or cyclohexenones.
A. J. Birch, J. Diekman and P. L. Macdonald, J. Chem. Soc. D, 1970, 52 DOI: 10.1039/C29700000052
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