Photochemical oxidation of plastoquinone-1, a model for the electron-transport quinones of plants, gives rise to the novel tricyclic peroxide, 4,5-dihydro-3,3,8,9-tetramethyl-4,9a-epoxy-9aH-1,2-benzodioxepin-7(3H)-one.
D. Creed, H. Werbin and E. T. Strom, J. Chem. Soc. D, 1970, 47 DOI: 10.1039/C29700000047
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