The presence of a CO stretching frequency at 1665 cm–1 in the i.r. spectrum of the 1 : 1 complex formed between trimethylalane and triphenylphosphoniumcyclopentadienylidemolybdenum tricarbonyl suggests co-ordinate covalent bonding between aluminium and the oxygen atom of one of the terminal carbonyl groups.
J. C. Kotz and C. D. Turnipseed, J. Chem. Soc. D, 1970, 41 DOI: 10.1039/C29700000041
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