A theoretical equation for the variation with solvent deuterium atom fraction n of the standard e.m.f. E°n of a cell containing the hydrogen gas and silver/silver chloride electrodes is derived and tested against the experimental results of Noonan and La Mer.1 The comparison is used to estimate the equilibrium constants for the reactions H2O(g)+ HD(g)= HDO(g)+ H2(g), and HDO(g)+ D2(g)= D2O(g)+ HD(g).
V. Gold and B. M. Lowe, Trans. Faraday Soc., 1969, 65, 3037 DOI: 10.1039/TF9696503037
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...