Volume 65, 1969

Absorption spectra of dimer cations. Part 1.—Olefins

Abstract

The absorption spectra of γ-irradiated glasses at 77 K containing cyclohexene, butadiene and penta-1,3-diene have been studied. The effects of warming and recooling and of concentration show that the bands can be assigned to monomeric and dimeric radical cations (M+ and M+2). Assignments of the corresponding spectra of a number of olefins obtained by other workers are discussed.

Article information

Article type
Paper

Trans. Faraday Soc., 1969,65, 2576-2581

Absorption spectra of dimer cations. Part 1.—Olefins

B. Badger and B. Brocklehurst, Trans. Faraday Soc., 1969, 65, 2576 DOI: 10.1039/TF9696502576

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