The thicknesses of first and second black soap films stabilized by the tetradecyltrimethylammonium cation in the presence of several anions and anion mixtures have been measured over a range of ionic strength. The critical conditions for the formation of second black films have been established; there is a close resemblance between second black film formation and the flocculation of a colloidal system.
G. Ibbotson and M. N. Jones, Trans. Faraday Soc., 1969, 65, 1146 DOI: 10.1039/TF9696501146
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