The absorption and magnetic circular dichroism spectra of the tetrachloro-cobaltate ion have been measured as a function of temperature in a single crystal. The major contribution to the Faraday effect of the 4A2→4T1(P) transition is temperature dependent. The source of this effect and the assignment of the spectra are discussed.
R. G. Denning and J. A. Spencer, Symp. Faraday Soc., 1969, 3, 84 DOI: 10.1039/SF9690300084
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