The total synthesis of racemic fumaricine and its epimer with respect to the configuration of the hydroxy-group is described. On the basis of physical properties, it is shown that the hydroxy-group in fumaricine is not hydrogen bonded to the nitrogen atom.
T. Kishimoto and S. Uyeo, J. Chem. Soc. C, 1969, 2600 DOI: 10.1039/J39690002600
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