Benzyl chlorides react with t-butyl-lithium in a mixture of pentane and hexane to give neopentylbenzenes, XC6H4·CH2But. Yields were (X =) H, 75; o-Me, 25; m-Me, 55; p-Me, 62; m-F, 70; p-F, 70; m-Cl, 60; p-Cl, 69; p-Br, 60%.
A. R. Bassindale, C. Eaborn and D. R. M. Walton, J. Chem. Soc. C, 1969, 2505 DOI: 10.1039/J39690002505
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