SCHEDULED MAINTENANCE
The synthesis of trans-ethyl 3,4,5-trimethoxyphenylglycidate (I) by the Darzens condensation is described and its configuration is deduced from n.m.r. analysis. The oxiran ring-opening reactions of (I) with alkylamines and ammonia in absolute ethanol were found to proceed with cleavage exclusively at the aryl-substituted oxiran carbon.
K. N. Parameswaran and O. M. Friedman, J. Chem. Soc. C, 1969, 1991 DOI: 10.1039/J39690001991
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...